The Compton effect describes the interaction of x-ray photons with electrons, in Compton's experiment in 1922/23 the electrons of graphite atoms. The x-ray photons scatter (Compton scattering) off the electrons in different directions. The remaining energy (lower frequency) of the scattered x-ray photons depends on the scattering angle. From an energy based point of view, these 'new or old' photons are a part of the original energy, represented by the incident x-ray photon before the interaction. The photons loss of energy (reduced frequency) is gained by an electron. Depending on this energy the electron could leave the atom. Depending on the remaining energy of the photon the interaction can repeat with a more to more decreasing energy level in the form of further Compton Scattering or by photo-electric absorption. Usually the Compton effect involves atom-bound electrons.
The Compton effect is responsible for most scattering effects in radiography.

The photoelectric effect describes the following interaction of electromagnetic radiation with a metallic surface: a photon with an energy (frequency) above the binding energy of an electron gets absorbed and the electron is emitted. The positive energy difference is transferred to the electrons kinetic energy. If the photons energy is not high enough for the electron to overcome its binding forces, the photon will be re-emitted. It is not the intensity of a photon beam (amount of photons) which allows the photoelectric effect; it is the energy (frequency) of a single photon which will allow the emission of a single photoelectron.
The discovery and study of the photoelectric effect leads to a new quantized understanding in physics. Albert Einstein was awarded the Noble prize for physics in 1921 'for his services to theoretical physics and especially for his discovery of the law of the photoelectric effect'.
The photoelectric effect is the most important effect in medical radiography. E.g. it is photoelectric absorption that is responsible for most of the absorption in a mammogram which creates the contrast in the image.

See also Photon, Electron.

X-rays are a part of the electromagnetic spectrum. X-rays and gamma rays are differentiated on the origin of the radiation, not on the wavelength, frequency, or the energy. X-rays are emitted by electrons outside the nucleus, while gamma rays are emitted by the nucleus. X-rays have wavelengths in the range of about 1 nanometer (nm) to 10 picometer (pm), frequencies in the range of 10^-16 to 10^-20 Hertz (Hz) and photon energies between 0.12 and 120 kilo electron Volt (keV). The energy of rays increase with decreased wavelengths. X-rays with energies between 10 keV and a few hundred keV are considered hard X-rays. The cutoff between soft or hard X-rays is around a wavelength of 100 pm.
Because of their short wavelength, X-rays interact little with matter and pass through a wide range of materials. These interactions occur as absorption or scattering;; primary are the photoelectric effect, Compton scattering and, for ultrahigh photon energies of above 1.022 mega electron Volt (MeV), pair production.
X-rays are produced when high energy electrons struck a metal target. The kinetic energy of the electrons is transformed into electromagnetic energy when the electrons are abruptly decelerated (also called bremsstrahlung radiation, or braking radiation) similar to the deceleration of the circulating electron beam in a synchrotron particle accelerator. Another type of rays is produced by the inner, more tightly bound electrons in atoms;; frequently occurring in decay of radionuclides (characteristic radiation, gamma ray, beta ray). The energy of an X-ray is equivalent to the difference in energy of the initial and final atomic state minus the binding energy of the electron.
Wilhelm Conrad Roentgen discovered this type of rays (also called Roentgen-rays) in 1895 and realized that X-rays penetrate soft tissue but are absorbed by bones, which provides the possibility to image anatomic structures; the first type of diagnostic imaging was established. Radiographic images are based on this difference in attenuation for tissue and organs of different density. Today ionizing radiation is widely used in medicine in the field of radiology.

See also Exposure Factors, X-Ray Tube, and X-Ray Spectrum.